It was painted when Harrison was a student so the sitter is most likely a model, probably at the RA Schools in London, and the canvas was used by the artist as an example of his skill when pitching for portrait commissions - though he later moved to Wales and painted landscapes.
All this from a long discussion on the Art Fund Art detective site, and a big credit to E.Jones who found the press report.
There are probably other pictures from this period featuring the same sitter, most likely in genre scenes, though maybe in similar head-and-shoulder studies.
Credit where it is due. It's not the Art Fund website, rather it is Art UK's Art Detective discussion forum.
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